Beyond the animal it carries, a branch enters three fixed sets of relations that the almanac and the fate-calculation tradition use constantly. Chou belongs to the trio Si, You and Chou, one of the four groups of three branches spaced four apart which are read as combining into Metal. It clashes with Wei, the branch six places away, and it forms one of the six harmonies with Zi. These relations are properties of position in the twelve, not of the animal.
The branches also do more work than the year cycle they are best known for. They divide the day into twelve double hours, so Chou names a period of two hours as well as a year and a month; they mark the twelve directions of the compass, Chou standing at north-northeast; and they carry the twelve stations against which the movement of Jupiter was tracked, which is one proposed origin for the twelve-year cycle itself.
The stem-and-branch day count is the longest continuously running day count known. Numbering days by ganzhi begins in the Shang inscriptions and has run without acknowledged interruption since, through every dynastic change and every calendar reform, because the cycle of sixty is independent of any astronomical quantity and therefore needs no correction. Chinese historical dates from the classical period onward can be checked against it.
Chou is one of the four Earth branches, which stand at the close of each season in the month assignment and are read as the transitions between phases rather than as the seasons themselves. That gives the Earth branches a particular character in fate calculation, where they are often described as storehouses, holding the residue of the season that is ending.
Sources Chinese Mathematical Astrology: Reaching Out to the StarsHo Peng Yoke with The Chinese Sexagenary Cycle and the Ritual Origins of the CalendarAdam Smith