More dubious claims attach to this solid than to the other four together. They are not all of one kind, and they are worth separating.
Disputed, and largely rejected. Several hundred carved stone balls survive from Neolithic Scotland, dating to around the third millennium BC, and it is often asserted that they show knowledge of the five Platonic solids a thousand years before the Greeks. Mathematicians who have examined the claim reject it. The knob counts vary enormously, from three to more than a hundred and sixty, with six much the commonest; the photograph used to support the claim has bands added that do not follow the carving, and the objects shown are not the Ashmolean Museum balls they are said to be; no securely icosahedral example is known. The balls are genuine artefacts of unknown purpose. They are not a set of regular solids.
Genuinely unknown. Roughly 130 hollow bronze dodecahedra survive from the Roman provinces, from Britain to Hungary, dated between the second and fourth centuries AD, each face pierced by a hole of a different size. No ancient text mentions them and no ancient image shows one. Proposed uses run from surveying instruments and knitting frames to gaming pieces and ritual objects, with no present way to decide between them.
Serious, and superseded. In 2003 cosmologists led by Jean-Pierre Luminet proposed that space might be finite and shaped as a Poincare dodecahedral space, opposite faces identified after a twist, which would account for an observed shortage of large-angle correlations in the cosmic microwave background. This was legitimate physics and was tested as such: the Planck mission's analysis of cosmic topology found none of the matched circles the model requires, and excluded a fundamental domain small enough to be detectable. A dodecahedral universe much larger than the observable region cannot be ruled out, but neither can it be tested.
Modern attribution. Assignments of the dodecahedron to the third eye or crown chakra, to aether, to Jupiter or to the pineal gland come from twentieth-century esoteric writing and have no classical source. So does the claim that all five solids can be read out of Metatron's Cube: the thirteen-circle figure it is drawn from is old, the name and the extraction are recent, and the projections offered for the dodecahedron and the icosahedron are not exact.
Sources Neolithic Carved Stone PolyhedraGeorge W. Hart with A Functional Reassessment of Roman Dodecahedra as Tools for Forming Standardised Wax ObjectsGreg Lamb, Planck 2013 results. XXVI. Background geometry and topology of the UniversePlanck Collaboration, Rainbow Body: A History of the Western Chakra System from Blavatsky to BrennanKurt Leland, The Ancient Secret of the Flower of Life, Volume 1Drunvalo Melchizedek